钢基电解水制氢催化剂的研究进展

doi:10.16507/j.issn.1006-6055.2021.11.001

世界科技研究与发展 ›› 2022, Vol. 44 ›› Issue (4): 466-481.doi: 10.16507/j.issn.1006-6055.2021.11.001

钢基电解水制氢催化剂的研究进展

吴明珠1,2 杨义斌1,2 卢立娟1,2 常禹1,2 陈瑞雪1,2 赵洋洋1,2 宋阳1,2 董莉娟1 李应1,2

1.化工污染防治重庆市高等职业技术院校应用技术推广中心，重庆401120；2.重庆工业职业技术学院化学与制药工程学院，重庆401120

出版日期:2022-08-25 发布日期:2022-09-01
基金资助:
重庆市自然科学基金“含镍不锈钢的同位改性及其电催化全解水的HER-OER双功能研究”“抗新型冠状病毒药物磷酸氯喹关键中间体的电化学合成”(cstc2019jcyj-msxmX0845，cstc2020jcyj-msxmX0056)

Research Process of Steel-based Electrocatalysts for Water Splitting to Produce Hydrogen

WU Mingzhu1,2 YANG Yibin1,2 LU Lijuan1,2 CHANG Yu1,2 CHEN Ruixue1,2 ZHAO Yangyang1,2 SONG Yang1,2 DONG Lijuan1 LI Ying1,2

1. Chemical Pollution Control Chongqing Applied Technology Extension Center of Higher Vocational Colleges, Chongqing 401120, China; 2. School of Chemical and Pharmaceutical Engineering, Chongqing Industry Polytechnic College, Chongqing 401120, China

Online:2022-08-25 Published:2022-09-01

摘要/Abstract

摘要：

廉价电催化剂是电解水制氢的研究热点之一。目前，针对钢基电解水制氢催化剂的系统性分析尚不充分。本文归纳了近４０年来不锈钢、低碳钢等钢基电解水制氢电催化剂的研究进展，分别对其作为析氧电催化剂、析氢电催化剂、析氢-析氧双功能电催化剂进行了介绍和剖析。通过对钢基电催化剂的不同制备方法、制备流程以及电催化反应条件等的分析，指出了其作为阳极析氧以及阴极析氢的活性、稳定性和耐受性的影响因素，归纳了不同制备方法存在的问题和电催化剂的使用条件。分析发现，析氧电催化剂和析氢析氧双功能电催化剂主要以不锈钢为基体制备而成，而析氢电催化剂则主要以低碳钢为基体制备而成。在此基础上，本文提出了后期研究钢基电催化剂的重点、方向以及改进方式，为制备高性能电解水制氢电催化剂及其工业化应用提供参考。

关键词: 钢, 水分解, 电催化剂, 析氧反应, 析氢反应

Abstract:

Inexpensive electrocatalysts are one of the research hotspots in the production of hydrogen from water electrolysis. There are few systematic summaries the steel-based electrocatalyst for water splitting. This review summarized the research status of steel-based electrocatalysts (stainless steel, low-carbon steel and other steels) in the past 40 years, and introduced them as oxygen evolution electrocatalysts, hydrogen evolution electrocatalysts, dual-function electrocatalysts. In this paper, the different preparation methods, fabrication processes and electrocatalytic reaction conditions were analysized. Meanwhile, the influencing factors of the activity, stability and tolerance of oxygen evolution at anode and hydrogen evolution at cathode were summarized. It was found that the oxygen evolution electrocatalyst and the hydrogen-oxygen evolution bifunctional electrocatalyst were mainly prepared with stainless steel as the matrix, while the hydrogen evolution electrocatalyst was prepared with the low carbon steelas the matrix. Furthermore, advantages and disadvantages of fabrication methods and further research focus were discussed. The in-depth understanding provides the guidance for the design of the high-performance water splitting electrocatalysts for industrial applications.

Key words: Steel, Electrocatalyst, Water Splitting, Oxygen Evolution Reaction, Hydrogen Evolution Reaction

吴明珠杨义斌卢立娟常禹陈瑞雪赵洋洋宋阳董莉娟李应. 钢基电解水制氢催化剂的研究进展[J]. 世界科技研究与发展, 2022, 44(4): 466-481.

WU Mingzhu YANG Yibin LU Lijuan CHANG Yu CHEN Ruixue ZHAO Yangyang SONG Yang DONG Lijuan LI Ying. Research Process of Steel-based Electrocatalysts for Water Splitting to Produce Hydrogen[J]. WORLD SCI-TECH R&D, 2022, 44(4): 466-481.

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钢基电解水制氢催化剂的研究进展

Research Process of Steel-based Electrocatalysts for Water Splitting to Produce Hydrogen

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